Kode risk and Kode safety

Risk phrases

• R1: Explosive when dry
• R2: Risk of explosion by shock, friction, fire or other sources of ignition
• R3: Extreme risk of explosion by shock, friction, fire or other sources of ignition
• R4: Forms very sensitive explosive metallic compounds
• R5: Heating may cause an explosion
• R6: Explosive with or without contact with air
• R7: May cause fire
  
• R8: Contact with combustible material may cause fire
• R9: Explosive when mixed with combustible material
• R10: Flammable
• R11: Highly flammable
• R12: Extremely flammable
• R14: Reacts violently with water
• R15: Contact with water liberates extremely flammable gases
• R16: Explosive when mixed with oxidising substances
• R17: Spontaneously flammable in air
• R18: In use, may form flammable/explosive vapour-air mixture
• R19: May form explosive peroxides
• R20: Harmful by inhalation
• R21: Harmful in contact with skin
• R22: Harmful if swallowed
• R23: Toxic by inhalation
• R24: Toxic in contact with skin
• R25: Toxic if swallowed
• R26: Very toxic by inhalation
• R27: Very toxic in contact with skin
• R28: Very toxic if swallowed
• R29: Contact with water liberates toxic gas.
• R30: Can become highly flammable in use
• R31: Contact with acids liberates toxic gas
• R32: Contact with acids liberates very toxic gas
• R33: Danger of cumulative effects
• R34: Causes burns
• R35: Causes severe burns
• R36: Irritating to eyes
• R37: Irritating to respiratory system
• R38: Irritating to skin
• R39: Danger of very serious irreversible effects
• R40: Limited evidence of a carcinogenic effect
• R41: Risk of serious damage to eyes
• R42: May cause sensitisation by inhalation
• R43: May cause sensitisation by skin contact
• R44: Risk of explosion if heated under confinement
• R45: May cause cancer
• R46: May cause heritable genetic damage
• R48: Danger of serious damage to health by prolonged exposure
• R49: May cause cancer by inhalation
• R50: Very toxic to aquatic organisms
• R51: Toxic to aquatic organisms
• R52: Harmful to aquatic organisms
• R53: May cause long-term adverse effects in the aquatic environment
• R54: Toxic to flora
• R55: Toxic to fauna
• R56: Toxic to soil organisms
• R57: Toxic to bees
• R58: May cause long-term adverse effects in the environment
• R59: Dangerous for the ozone layer
• R60: May impair fertility
• R61: May cause harm to the unborn child
• R62: Possible risk of impaired fertility
• R63: Possible risk of harm to the unborn child
• R64: May cause harm to breast-fed babies
• R65: Harmful: may cause lung damage if swallowed
• R66: Repeated exposure may cause skin dryness or cracking
• R67: Vapours may cause drowsiness and dizziness
• R68: Possible risk of irreversible effects

Combinations

• R14/15: Reacts violently with water, liberating extremely flammable gases
• R15/29: Contact with water liberates toxic, extremely flammable gases
• R20/21: Harmful by inhalation and in contact with skin
• R20/22: Harmful by inhalation and if swallowed
• R20/21/22: Harmful by inhalation, in contact with skin and if swallowed
• R21/22: Harmful in contact with skin and if swallowed
• R23/24: Toxic by inhalation and in contact with skin
• R23/25: Toxic by inhalation and if swallowed
• R23/24/25: Toxic by inhalation, in contact with skin and if swallowed
• R24/25: Toxic in contact with skin and if swallowed
• R26/27: Very toxic by inhalation and in contact with skin
• R26/28: Very toxic by inhalation and if swallowed
• R26/27/28: Very toxic by inhalation, in contact with skin and if swallowed
• R27/28: Very toxic in contact with skin and if swallowed
• R36/37: Irritating to eyes and respiratory system
• R36/38: Irritating to eyes and skin
• R36/37/38: Irritating to eyes, respiratory system and skin
• R37/38: Irritating to respiratory system and skin
• R39/23: Toxic: danger of very serious irreversible effects through inhalation
• R39/24: Toxic: danger of very serious irreversible effects in contact with skin
• R39/25: Toxic: danger of very serious irreversible effects if swallowed
• R39/23/24: Toxic: danger of very serious irreversible effects through inhalation and in contact with skin
• R39/23/25: Toxic: danger of very serious irreversible effects through inhalation and if swallowed
• R39/24/25: Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
• R39/23/24/25: Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
• R39/26: Very Toxic: danger of very serious irreversible effects through inhalation
• R39/27: Very Toxic: danger of very serious irreversible effects in contact with skin
• R39/28: Very Toxic: danger of very serious irreversible effects if swallowed
• R39/26/27: Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skin
• R39/26/28: Very Toxic: danger of very serious irreversible effects through inhalation and if swallowed
• R39/27/28: Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
• R39/26/27/28: Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
• R42/43: May cause sensitization by inhalation and skin contact
• R48/20: Harmful: danger of serious damage to health by prolonged exposure through inhalation
• R48/21: Harmful: danger of serious damage to health by prolonged exposure in contact with skin
• R48/22: Harmful: danger of serious damage to health by prolonged exposure if swallowed
• R48/20/21: Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
• R48/20/22: Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
• R48/21/22: Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
• R48/20/21/22: Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed
• R48/23: Toxic: danger of serious damage to health by prolonged exposure through inhalation
• R48/24: Toxic: danger of serious damage to health by prolonged exposure in contact with skin
• R48/25: Toxic: danger of serious damage to health by prolonged exposure if swallowed
• R48/23/24: Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
• R48/23/25: Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
• R48/24/25: Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
• R48/23/24/25: Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed
• R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
• R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
• R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
• R68/20: Harmful: possible risk of irreversible effects through inhalation
• R68/21: Harmful: possible risk of irreversible effects in contact with skin
• R68/22: Harmful: possible risk of irreversible effects if swallowed
• R68/20/21: Harmful: possible risk of irreversible effects through inhalation and in contact with skin
• R68/20/22: Harmful: possible risk of irreversible effects through inhalation and if swallowed
• R68/21/22: Harmful: possible risk of irreversible effects in contact with skin and if swallowed
• R68/20/21/22: Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed

Kode safety

• (S1): Keep locked up
• (S2): Keep out of the reach of children
• S3: Keep in a cool place
• S4: Keep away from living quarters
• S5: Keep contents under ... (appropriate liquid to be specified by the manufacturer)
• S6: Keep under ... (inert gas to be specified by the manufacturer)
• S7: Keep container tightly closed
• S8: Keep container dry
• S9: Keep container in a well-ventilated place
• S10: Keep contents wet
• S11: Avoid contact with air
• S12: Do not keep the container sealed
• S13: Keep away from food, drink and animal foodstuffs
• S14: Keep away from ... (incompatible materials to be indicated by the manufacturer)
• S15: Keep away from heat
• S16: Keep away from sources of ignition - No smoking
• S17: Keep away from combustible material
• S18: Handle and open container with care
• S20: When using do not eat or drink
• S21: When using do not smoke
• S22: Do not breathe dust
• S23: Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer)
• S24: Avoid contact with skin
• S25: Avoid contact with eyes
• S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
• S27: Take off immediately all contaminated clothing
• S28: After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
• S29: Do not empty into drains
• S30: Never add water to this product
• S33: Take precautionary measures against static discharges
• S35: This material and its container must be disposed of in a safe way
• S36: Wear suitable protective clothing
• S37: Wear suitable gloves
• S38: In case of insufficient ventilation wear suitable respiratory equipment
• S39: Wear eye/face protection
• S40: To clean the floor and all objects contaminated by this material use ... (to be specified by the manufacturer)
• S41: In case of fire and/or explosion do not breathe fumes
• S42: During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified by the manufacturer)
• S43: In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
• S45: In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
• S46: If swallowed, seek medical advice immediately and show this container or label
• S47: Keep at temperature not exceeding ... °C (to be specified by the manufacturer)
• S48: Keep wet with ... (appropriate material to be specified by the manufacturer)
• S49: Keep only in the original container
• S50: Do not mix with ... (to be specified by the manufacturer)
• S51: Use only in well-ventilated areas
• S52: Not recommended for interior use on large surface areas
• S53: Avoid exposure - obtain special instructions before use
• S56: Dispose of this material and its container at hazardous or special waste collection point
• S57: Use appropriate containment to avoid environmental contamination
• S59: Refer to manufacturer/supplier for information on recovery/recycling
• S60: This material and its container must be disposed of as hazardous waste
• S61: Avoid release to the environment. Refer to special instructions/safety data sheet
• S62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label
• S63: In case of accident by inhalation: remove casualty to fresh air and keep at rest
• S64: If swallowed, rinse mouth with water (only if the person is conscious)

Combinations

• (S1/2): Keep locked up and out of the reach of children
• S3/7: Keep container tightly closed in a cool place
• S3/7/9: Keep container tightly closed in a cool, well-ventilated place
• S3/9/14: Keep in a cool, well-ventilated place away from ... (incompatible materials to be indicated by the manufacturer)
• S3/9/14/49: Keep only in the original container in a cool, well-ventilated place away from ... (incompatible materials to be indicated by the manufacturer)
• S3/9/49: Keep only in the original container in a cool, well-ventilated place
• S3/14 Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer)
• S7/8: Keep container tightly closed and dry
• S7/9: Keep container tightly closed and in a well-ventilated place
• S7/47: Keep container tightly closed and at temperature not exceeding ... °C (to be specified by the manufacturer)
• S8/10: Keep container wet, but keep the contents dry
• S20/21: When using do not eat, drink or smoke
• S24/25: Avoid any inhalation, contact with skin and eyes. Wear suitable protective clothing and gloves
• S27/28: After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty of ... (to be specified by the manufacturer)
• S29/35: Do not empty into drains; dispose of this material and its container in a safe way
• S29/56: Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point
• S36/37: Wear suitable protective clothing and gloves
• S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
• S36/39: Wear suitable protective clothing and eye/face protection
• S37/39: Wear suitable gloves and eye/face protection
• S47/49: Keep only in the original container at temperature not exceeding ... °C (to be specified by the manufacturer)